30 05 600 Adhesive kit, window glass
|
|
30 05 600 Adhesive kit, window glass
|
Dual-component (2K-PUR).
|
-
|
Adhesive Betamate E2400, cartridge contains 2x225 ml.
|
|
-
|
Glass activator Betawipe 04604 (yellow lid) with applicator for the glass, 15 ml can.
|
|
-
|
Glass primer Betaprime 5001 (green lid) with applicator for the glass, 15 ml can.
|
|
-
|
RIM-activator Betawipe 4000 (blue lid), which is a special primer for imbedded glass, with applicator and wiper, 15 ml can.
|
|
-
|
Lint-free cloth and spout for applying adhesive.
|
Windscreen: Saab 9000/900 M94-/9-3/9-5.
Rear window: Saab 9000/900 M94-/9-3/9-5.
1
The product is classified as dangerous goods when transporting. Special regulations apply to packaging, marking and transport, therefore existing lead times cannot be guaranteed.
This product is extremely flammable and will irritate eyes and respiratory system. Contains isocyanates. Do not breathe vapours/mist. Avoid contact with eyes and skin. Store package in well-ventilated place. Keep away from sources of ignition - No smoking.
|
Material safety data sheet
|
|
1.
|
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product name
|
BETAMATE E2400 A
|
Manufacturer - supplier
|
SAAB-ANA Konsult AB
Box 1030
611 29 NYKÖPING
Tel: +46 (0) 155-24 94 50
Tel (emergency): 112
|
|
|
2.
|
COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient
|
CAS-no.
|
Content (%)
|
FM
|
FB
|
FH
|
R-phrases
|
Methylene diphenyl diisocyanate
|
101-68-8
|
0.1-1
|
|
|
Xn
|
20-36/37/38-42/43
|
Carbon black
|
1333-86-4
|
1-30
|
|
|
|
|
Key
|
FB/FH/FM = Hazard code for fire/health/environment
T+ = Very toxic
T = Toxic
C = Corrosive
Xn = Harmful
Xi = Irritant
V = Moderately harmful
IK = Not subject to labelling
E = Explosive
O = Oxidizing
F+ = Extremely flammable
F = Highly flammable
N = Dangerous for the environment
|
|
|
3.
|
HAZARDS IDENTIFICATION
Health hazards
|
Irritating to skin and respiratory system. May cause sensitisation and allergic reaction by inhalation and skin contact.
|
|
|
4.
|
FIRST AID MEASURES
Other information
|
Take off contaminated clothing immediately.
|
Inhalation
|
Move the casualty into fresh air. Seek medical advice in case of pronounced discomfort.
|
Skin
|
Wash skin immediately with soap and water. Seek medical advice if irritation persists.
|
Eyes
|
Flush eyes immediately with plenty of water. Hold eyes wide open. Seek medical advice if irritation persists.
|
Ingestion
|
Do not induce vomiting. Seek medical advice immediately.
|
|
|
5.
|
FIRE-FIGHTING MEASURES
Suitable extinguishing media
|
All standard extinguishing medium can be used.
|
Fire/explosions risks
|
In case of fire, toxic and irritating fumes can form (carbon and nitrous oxides, hydrogen cyanide).
|
Special protective equipment for firefighters
|
Complete protective equipment including respiratory equipment.
|
Other information
|
Do not breathe fumes from the fire. Move containers in the vicinity of the fire immediately or cool with water.
|
|
|
6.
|
SPILLAGE/ACCIDENTAL RELEASE MEASURES
Personal precautions
|
Avoid contact with skin, eyes and clothes. Do not breathe vapours. Wear the prescribed protective equipment (see heading 8).
|
Environmental precautions
|
Keep the product away from drains, the ground and watercourses.
|
Methods for cleaning up
|
Soak up using non-flammable absorbent material such as sand, earth, kieselguhr or vermikulite. Place in suitable container. Dispose of as directed under heading 13.
|
Other information
|
Ensure adequate ventilation. Keep unauthorised persons away from spillages. Warning for slippery surface.
|
|
|
7.
|
HANDLING AND STORAGE
Advice for safe handling
|
Avoid contact with eyes, skin and clothing. Do not breathe vapours. Use only in well ventilated areas. Mechanical ventilation and spot extraction may be necessary.
|
Storage
|
Store in a dry, well-ventilated place. Keep cool and dry, away from food, drink and animal feeding stuffs. Unauthorised persons should not have access to the storage area. Keep in original packaging. Keep container tightly closed.
|
|
|
8.
|
EXPOSURE CONTROLS/PERSONAL PROTECTION
Chemical substance
|
Limit
|
Methylene diphenyl diisocyanate
|
0.05 mg/m
3
|
Carbon black
|
3 mg/m
3
|
Control procedures
|
Use only in well-ventilated areas. Spot extraction equipment or mechanical ventilation may be necessary. Do not smoke, eat or drink while working with the product. Good personal hygiene is essential. Wash hands before taking a break and on completion of the work. Take off contaminated clothing immediately. A barrier cream can be used.
|
Respiratory equipment
|
A full-face or half-face mask with filter for organic vapours must be used in case of high vapour concentrations or if ventilation is inadequate.
|
Eye protection
|
Close-fitting protective glasses with side shields must be used if there is a risk of direct contact or splashing.
|
Protective gloves
|
We recommend users to wear protective rubber gloves. A barrier cream can be used on the skin.
|
Skin and body protection
|
Wear appropriate protective clothing.
|
|
|
9.
|
PHYSICAL AND CHEMICAL PROPERTIES
Form/state
|
Paste
|
Odour
|
of solvent
|
Colour
|
Black
|
Solubility in water
|
Insoluble
|
Density
|
approx. 1.22 g/cm
3
|
Flash point
|
>100 °C
|
Viscosity
|
approx. 50 g/min/23°C/3 bar/4 mm
|
|
|
|
|
10.
|
STABILITY AND REACTIVITY
Stability
|
Can react with the moisture in the air. Keep away from moisture.
|
Reacts with
|
Keep away from other chemical products. Keep away from strong acids, amines, alcohols and oxidizing agents. Keep away from water.
|
Hazardous decomposition products
|
In case or fire or intense heat, carbon dioxide, carbon monoxide, nitrous oxides and toxic fumes are produced.
|
|
|
11.
|
TOXICOLOGICAL INFORMATION
Inhalation
|
Irritating to the respiratory system. Inhalation of vapours may cause sensitisation with asthmatic breathing difficulties.
|
Skin
|
Irritating to the skin. Repeated exposure can lead to hypersensitivity and allergic reactions (eczema).
|
Eyes
|
Irritating.
|
Ingestion
|
If swallowed, may cause stinging in mouth and throat, nausea and stomach pains.
|
Sensitization
|
May cause sensitisation after inhalation or skin contact.
|
|
|
12.
|
ECOLOGICAL INFORMATION
Mobility
|
Insoluble in water.
|
Degradability
|
Data not available.
|
Bioaccumulation
|
Data not available.
|
Ecotoxicity
|
Data not available.
|
Other information
|
Do not empty into water, drains or onto ground.
|
|
|
13.
|
DISPOSAL CONSIDERATIONS
Disposal considerations
|
Dispose of product waste as hazardous waste in accordance with regulations. Recommended method of destruction: incineration in facilities with flue-gas purification.
|
EWC codes
|
08 04 09
waste adhesives and sealants containing organic solvents or other dangerous substances.
20 01 27
paint, inks, adhesives and resins containing dangerous substances.
|
Other information
|
Other codes may be relevant under certain circumstances.
|
|
|
14.
|
TRANSPORT INFORMATION
Transport information
|
Not classed as hazardous goods in accordance with current regulations.
|
|
|
15.
|
REGULATORY INFORMATION
Labelling
|
Harmful
|
Content
|
Contains isocyanates. See information from manufacturer.
|
References
|
See provisions of the Swedish National Board of Occupational Safety and Health on thermosetting plastics.
|
R-phrases
|
R42
|
May cause sensitisation by inhalation
|
S-phases
|
S2
|
Keep out of the reach of children.
|
|
|
S23
|
Do not breathe vapour/spray
|
|
|
S45
|
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
|
|
|
S51
|
Use only in well-ventilated areas.
|
|
|
16.
|
OTHER INFORMATION
General information
|
This material safety data sheet is only intended to provide guidance as to safe handling with regard to health, safety and the environment. The information contained in this material safety data sheet is not a specification of the product and must not be considered as a guarantee of any specific properties.
|
Issued
|
2001-05-02
|
|
|
Material safety data sheet
|
|
1.
|
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product name
|
BETAMATE E2400 B
|
Manufacturer - supplier
|
SAAB-ANA Konsult AB
Box 1030
611 29 NYKÖPING
Tel: +46 (0) 155-24 94 50
Tel (emergency): 112
|
|
|
2.
|
COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient
|
CAS-no.
|
Content (%)
|
FM
|
FB
|
FH
|
R-phrases
|
Diisononylphtalate
|
28553-12-0
|
10-30
|
|
|
|
|
2-mercaptoethanol
|
60-24-2
|
0.1-3
|
N
|
|
T
|
R22-24-34-51/53
|
Carbon black
|
1333-86-4
|
5-20
|
|
|
|
|
Key
|
FB/FH/FM = Hazard code for fire/health/environment
T+ = Very toxic
T = Toxic
C = Corrosive
Xn = Harmful
Xi = Irritant
V = Moderately harmful
IK = Not subject to labelling
E = Explosive
O = Oxidizing
F+ = Extremely flammable
F = Highly flammable
N = Dangerous for the environment
|
|
|
3.
|
HAZARDS IDENTIFICATION
Health hazards
|
The product defats the skin and may after prolonged or repeated contact cause irritation.
|
|
|
4.
|
FIRST AID MEASURES
Other information
|
Take off contaminated clothing immediately.
|
Inhalation
|
Move the casualty into fresh air. Seek medical advice in case of pronounced discomfort.
|
Skin
|
Wash skin immediately with soap and water. Seek medical advice if irritation persists.
|
Eyes
|
Flush eyes immediately with plenty of water. Hold eyes wide open. Seek medical advice if irritation persists.
|
Ingestion
|
Do not induce vomiting. Seek medical advice immediately.
|
|
|
5.
|
FIRE-FIGHTING MEASURES
Suitable extinguishing media
|
All standard extinguishing medium can be used.
|
Fire/explosions risks
|
In case of fire, toxic and irritating fumes can form (carbon, nitrous and sulphur oxides).
|
Special protective equipment for firefighters
|
Complete protective equipment including respiratory equipment.
|
Other information
|
Do not breathe fumes from the fire. Move containers in the vicinity of the fire immediately or cool with water.
|
|
|
6.
|
SPILLAGE/ACCIDENTAL RELEASE MEASURES
Personal precautions
|
Avoid contact with skin, eyes and clothes. Do not breathe vapours. Wear the prescribed protective equipment (see heading 8).
|
Environmental precautions
|
Keep the product away from drains, the ground and watercourses.
|
Methods for cleaning up
|
Soak up using non-flammable absorbent material such as sand, earth, kieselguhr or vermikulite. Place in suitable container. Dispose of as directed under heading 13.
|
Other information
|
Ensure adequate ventilation. Keep unauthorised persons away from spillages. Warning for slippery surface.
|
|
|
7.
|
HANDLING AND STORAGE
Advice for safe handling
|
Avoid contact with eyes, skin and clothing. Do not breathe vapours. Use only in well ventilated areas. Mechanical ventilation and spot extraction may be necessary.
|
Storage
|
Store in a dry, well-ventilated place. Keep cool and dry, away from food, drink and animal feeding stuffs. Keep in original packaging. Keep container tightly closed.
|
|
|
8.
|
EXPOSURE CONTROLS/PERSONAL PROTECTION
Chemical substance
|
Limit
|
Carbon black
|
3 mg/m
3
|
Control procedures
|
Use only in well-ventilated areas. Spot extraction equipment or mechanical ventilation may be necessary. Do not smoke, eat or drink while working with the product. Good personal hygiene is essential. Wash hands before taking a break and on completion of the work. Take off contaminated clothing immediately. A barrier cream can be used.
|
Respiratory equipment
|
A full-face or half-face mask with filter for organic vapours must be used in case of high vapour concentrations or if ventilation is inadequate.
|
Eye protection
|
Close-fitting protective glasses with side shields must be used if there is a risk of direct contact or splashing.
|
Protective gloves
|
We recommend users to wear protective rubber gloves. A barrier cream can be used on the skin.
|
Skin and body protection
|
Wear appropriate protective clothing.
|
|
|
9.
|
PHYSICAL AND CHEMICAL PROPERTIES
Form/state
|
Paste
|
Odour
|
Mild
|
Colour
|
Black
|
Solubility in water
|
Insoluble
|
Density
|
approx. 1.27 g/cm
3
|
Flash point
|
>100 °C
|
Viscosity
|
approx. 18 g/min/23°C/3 bar/4 mm
|
|
|
|
|
10.
|
STABILITY AND REACTIVITY
Stability
|
Stable under normal conditions.
|
Reacts with
|
Avoid contact with other chemical products. Avoid contact with oxidizing agents.
|
Hazardous decomposition products
|
In case or fire or intense heat, carbon dioxide, carbon monoxide, nitrous oxides, sulphur oxides and other toxic fumes are produced.
|
|
|
11.
|
TOXICOLOGICAL INFORMATION
Inhalation
|
May irritate the respiratory system.
|
Skin
|
May irritate the skin. Repeated exposure may cause redness, stinging and dermatitis.
|
Eyes
|
Irritating.
|
Ingestion
|
If swallowed, may cause stinging in mouth and throat, nausea and stomach pains.
|
|
|
12.
|
ECOLOGICAL INFORMATION
Mobility
|
Insoluble in water.
|
Degradability
|
Data not available.
|
Bioaccumulation
|
Data not available.
|
Ecotoxicity
|
Data not available.
|
Other information
|
Do not empty into water, drains or onto ground.
|
|
|
13.
|
DISPOSAL CONSIDERATIONS
Disposal considerations
|
Dispose of product waste as hazardous waste in accordance with regulations. Recommended method of destruction: incineration in facilities with flue-gas purification.
|
EWC codes
|
08 04 09
waste adhesives and sealants containing organic solvents or other dangerous substances.
20 01 27
paint, inks, adhesives and resins containing dangerous substances.
|
Other information
|
Other codes may be relevant under certain circumstances.
|
|
|
14.
|
TRANSPORT INFORMATION
Transport information
|
Not classed as hazardous goods in accordance with current regulations.
|
|
|
15.
|
REGULATORY INFORMATION
References
|
Not classified as harmful or dangerous for the environment.
|
R-phrases
|
|
N/A
|
S-phases
|
|
N/A
|
|
|
16.
|
OTHER INFORMATION
General information
|
This material safety data sheet is only intended to provide guidance as to safe handling with regard to health, safety and the environment. The information contained in this material safety data sheet is not a specification of the product and must not be considered as a guarantee of any specific properties.
|
Issued
|
2001-05-07
|
|
|
Material safety data sheet
|
|
1.
|
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product name
|
BETAWIPE VP04604
|
Manufacturer - supplier
|
SAAB-ANA Konsult AB
Box 1030
611 29 NYKÖPING
Tel: +46 (0) 155-24 94 82
Fax: +46 (0) 155-24 94 71
Tel (emergency): 112
|
|
|
2.
|
COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient
|
CAS-no.
|
Content (%)
|
FM
|
FB
|
FH
|
R-phrases
|
3-mercaptopropyl-trimethoxysilane
|
4420-74-0
|
1-10
|
N
|
|
Xn
|
R21/22-51/53
|
3-(2-aminoethylamino)propyltrimethoxysilane
|
1760-24-3
|
1-10
|
|
|
Xi
|
R36/38-43
|
Isopropanol
|
67-63-0
|
80-100
|
|
F+
|
Xi
|
R11-36-67
|
Key
|
FB/FH/FM = Hazard code for fire/health/environment
T+ = Very toxic
T = Toxic
C = Corrosive
Xn = Harmful
Xi = Irritant
V = Moderately harmful
IK = Not subject to labelling
E = Explosive
O = Oxidizing
F+ = Extremely flammable
F = Highly flammable
N = Dangerous for the environment
|
|
|
3.
|
HAZARDS IDENTIFICATION
Health hazards
|
Irritating to eyes, skin and respiratory system. May cause sensitisation and allergic reaction after skin contact. Breathing high concentrations may cause dizziness, headaches and nausea. Defats the skin and after prolonged or repeated contact cause the skin to dry and crack.
|
Fire hazards
|
Highly flammable.
|
|
|
4.
|
FIRST AID MEASURES
Other information
|
Take off contaminated clothing immediately.
|
Inhalation
|
Move the casualty into fresh air. Seek medical advice immediately. Keep the casualty warm and allow to rest. Perform artificial respiration if the casualty stops breathing or breathes irregularly.
|
Skin
|
Wash skin immediately with soap and water. Seek medical advice if irritation persists.
|
Eyes
|
Flush eyes immediately with plenty of water for several minutes. Hold eyes wide open. Seek medical advice immediately.
|
Ingestion
|
Do not induce vomiting. Seek medical advice immediately.
|
|
|
5.
|
FIRE-FIGHTING MEASURES
Suitable extinguishing media
|
Alcohol-resistant foam, carbon dioxide or water spray.
|
Unsuitable extinguishing media
|
Water jet.
|
Fire/explosions risks
|
Vapours can form an explosive mixture with air. In case of fire, flammable and irritating gases can form.
|
Special protective equipment for firefighters
|
Complete protective equipment including respiratory equipment.
|
Other information
|
Do not breathe fumes from the fire. Move containers in the vicinity of the fire immediately or cool with water.
|
|
|
6.
|
SPILLAGE/ACCIDENTAL RELEASE MEASURES
Personal precautions
|
Avoid contact with skin, eyes and clothes. Do not breathe vapours. Wear the prescribed protective equipment (see heading 8).
|
Environmental precautions
|
Keep the product away from drains, the ground and watercourses. Contact the appropriate authority immediately if the product enters drains, lakes or watercourses.
|
Methods for cleaning up
|
Soak up using non-flammable absorbent material such as sand, earth, kieselguhr or vermikulite. Dispose of as directed under heading 13.
|
Other information
|
Remove all sources of ignition - No smoking. Provide good ventilation. Keep unauthorized persons away from the spillage. Warning for slippery surface.
|
|
|
7.
|
HANDLING AND STORAGE
Special properties and risks
|
The vapours are heavier than air and collect at floor level and low-lying areas. Flammable vapours that can combine with air to form an explosive mixture are produce at room temperature.
|
Advice for safe handling
|
Avoid contact with eyes, skin and clothing. Do not breathe vapours. Use only in well ventilated areas. Mechanical ventilation and spot extraction may be necessary. Store away from direct sunlight, heat, fire and other sources of ignition. Take precautionary measures against static discharges. Use only electrical equipment with explosion protection. See the instructions on the label.
|
Storage instructions
|
Store in a dry, well-ventilated place away from heat, fire and direct sunlight. No smoking. Electrical installations and equipment must have explosion protection. Follow regulations for storage of flammable liquids. Keep cool and dry, away from food, drink and animal feeding stuffs. Unauthorised persons must not have access to the storage area. Keep in original packaging. Keep container tightly closed.
|
|
|
8.
|
EXPOSURE CONTROLS/PERSONAL PROTECTION
Substance
|
Limit
|
Isopropanol
|
350 mg/m
3
|
Control procedures
|
Use only in well-ventilated areas. Spot extraction equipment or mechanical ventilation may be necessary. Do not smoke, eat or drink while working with the product. Good personal hygiene is essential. Wash hands before taking a break and on completion of the work. Take off contaminated clothing immediately. The use of a barrier cream is recommended.
|
Respiratory equipment
|
A full-face or half-face mask with filter for organic vapours must be used in case of high vapour concentrations or if ventilation is inadequate.
|
Eye protection
|
Close-fitting protective glasses with side shields must be used if there is a risk of direct contact or splashing.
|
Protective gloves
|
Solvent-resistant gloves. Use a barrier cream on skin.
|
Skin and body protection
|
Wear protective clothing if there is a risk of direct contact or splashes.
|
|
|
9.
|
PHYSICAL AND CHEMICAL PROPERTIES
Form/state
|
Liquid
|
Odour
|
Alcohol
|
Colour
|
Colourless
|
Solubility in water
|
Miscible
|
Density
|
0.79 g/cm
3
|
Boiling point
|
82 °C
|
Flash point
|
13 °C
|
Explosion limits
|
2-12 vol. %
|
Vapour pressure
|
approx. 40 mbar at 20°C
|
Viscosity
|
approx. 50 s/23°C/2 mm
|
Autoignition point
|
approx. 425°C
|
Vapour density (air=1)
|
2.1
|
|
|
10.
|
STABILITY AND REACTIVITY
Stability
|
Vapours can form explosive mixture with air.
|
Reacts with
|
Avoid contact with strong oxidizing agents.
|
Hazardous decomposition products
|
In case or fire or intense heat, carbon dioxide, carbon monoxide and toxic fumes are produced.
|
|
|
11.
|
TOXICOLOGICAL INFORMATION
Inhalation
|
Irritating to the respiratory system. Inhalation may cause headaches, dizziness, drowsiness, muscular weakness, narcotic effects and, in exceptional cases, unconsciousness. Inhalation of high concentrations may damage the lever and kidneys and affect the central nervous system.
|
Skin
|
Prolonged or repeated skin contact defats the skin and may cause irritation and dermatitis. Repeated exposure can cause sensitization and allergic reactions (eczema).
|
Eyes
|
Irritating to the eyes and may cause temporary damage.
|
Ingestion
|
If swallowed, may cause stinging in mouth and throat, nausea and stomach pains as well as similar effect to inhalation.
|
Sensitization
|
Sensitizing effects possible after skin contact.
|
|
|
12.
|
ECOLOGICAL INFORMATION
Degradability
|
The solvent, isopropanol, decomposes readily. The product also contains substances that do not readily decompose.
|
Bioaccumulation
|
The solvent, isopropanol, does not bioaccumulate. Data lacking for other components.
|
Ecotoxicity
|
Fish toxicity: LC50 > 100 mg/l (regarding isopropanol)
|
Other information
|
Do not empty into water, drains or onto ground.
|
|
|
13.
|
DISPOSAL CONSIDERATIONS
Disposal considerations
|
Dispose of product waste as hazardous waste in accordance with regulations. Recommended method of destruction: incineration in facilities with flue-gas purification. EWC-code 07 01 04, other organic solvents, washing liquids and mother liquors. EWC-code 07 06 04, other organic solvents, washing liquids and mother liquors.
|
|
|
14.
|
TRANSPORT INFORMATION
Road (ADR)
|
UN-no.:
1219
Hazardous goods
Marg no.
|
Class:
3, 3 (b)
|
Label
Hazard no.
|
Rail (RID)
|
UN-no.:
1219
|
Class:
3, 3 (b)
|
Label
Hazard no.
|
Sea (IMDG)
|
UN-no.:
1219
Hazardous goods
Class:
3.2
EmS:
3-06
|
Page
MFAG:
305
Label
Marine poll:
No
|
Packaging group:
II
Sub. Risk
|
IATA (air)
|
UN-no.:
1219
Hazardous goods
|
Class:
3
Sub. Risk
|
Label
Packaging group:
II
|
Proper shipping name
|
Isopropanol mixture
|
|
|
15.
|
REGULATORY INFORMATION
Labelling
|
Irritant, Highly flammable
|
R-phrases
|
R11
|
Highly flammable.
|
|
|
R36
|
Irritating to eyes.
|
|
|
R43
|
May cause sensitization by skin contact.
|
|
|
R67
|
Vapours may cause drowsiness and dizziness.
|
S-phases
|
S2
|
Keep out of the reach of children.
|
|
|
S7
|
Keep container tightly closed
|
|
|
S16
|
Keep away from sources of ignition - No smoking.
|
|
|
S26
|
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
|
|
|
S36/37
|
Wear suitable protective clothing and gloves.
|
|
|
S46
|
If swallowed, seek medical advice immediately and show this container or label.
|
|
|
16.
|
OTHER INFORMATION
General information
|
This material safety data sheet is only intended to provide guidance as to safe handling with regard to health, safety and the environment. The information contained in this material safety data sheet is not a specification of the product and must not be considered as a guarantee of any specific properties.
|
Issued
|
2001-05-07
|
|
|
Material safety data sheet
|
|
1.
|
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product name
|
BETAPRIME 5001
|
Manufacturer - supplier
|
SAAB-ANA Konsult AB
Box 1030
611 29 NYKÖPING
Tel: +46 (0) 155-24 94 82
Fax: +46 (0) 155-24 94 71
Tel (emergency): 112
|
|
|
2.
|
COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient
|
CAS-no.
|
Content (%)
|
FM
|
FB
|
FH
|
R-phrases
|
Carbon black
|
1333-86-4
|
1-15
|
|
|
|
|
Ethylacetate
|
41-78-6
|
1-10
|
|
|
Xi
|
R11-36-66-67
|
Toluene
|
108-88-3
|
1-12.5
|
|
|
Xn
|
R20
|
Methoxybutyl acetate
|
4435-53-4
|
1-20
|
|
|
Xi
|
R36
|
Methyl ethyl ketone
|
78-93-3
|
20-50
|
|
|
Xi
|
R36-66-67
|
Solvent naphtha (petroleum), light
|
64742-95-6
|
1-2
|
N
|
|
Xn
|
R10-65-37-66-517/5
|
Key
|
FB/FH/FM = Hazard code for fire/health/environment
T+ = Very toxic
T = Toxic
C = Corrosive
Xn = Harmful
Xi = Irritant
V = Moderately harmful
IK = Not subject to labelling
E = Explosive
O = Oxidizing
F+ = Extremely flammable
F = Highly flammable
N = Dangerous for the environment
|
|
|
3.
|
HAZARDS IDENTIFICATION
Health hazards
|
Irritating to eyes. Defats the skin and after prolonged or repeated contact may cause skin to dry and crack. Inhalation of high concentrations may cause dizziness, headaches and nausea.
|
Fire hazards
|
Highly flammable.
|
|
|
4.
|
FIRST AID MEASURES
Other information
|
Take off contaminated clothing immediately.
|
Inhalation
|
Move the casualty into fresh air. Seek medical advice immediately. Effects may be delayed. Keep the casualty warm and allow to rest. Perform artificial respiration if the casualty stops breathing or breathes irregularly.
|
Skin
|
Wash skin immediately with soap and water. Seek medical advice if irritation persists.
|
Eyes
|
Flush eyes immediately with plenty of water for several minutes. Hold eyes wide open. Seek medical advice immediately.
|
Ingestion
|
Do not induce vomiting. Seek medical advice immediately.
|
|
|
5.
|
FIRE-FIGHTING MEASURES
Suitable extinguishing media
|
Foam or powder. Large fires can be extinguished with water spray.
|
Fire/explosions risks
|
Vapours can form an explosive mixture with air. In case of fire, harmful and irritating gases can form (e.g. carbon and nitrous oxides).
|
Special protective equipment for firefighters
|
Complete protective equipment including respiratory equipment
|
Other information
|
Do not breathe fumes from the fire. Move containers in the vicinity of the fire immediately or cool with water.
|
|
|
6.
|
SPILLAGE/ACCIDENTAL RELEASE MEASURES
Personal precautions
|
Avoid contact with skin, eyes and clothes. Do not breathe vapours. Wear the prescribed protective equipment (see heading 8).
|
Environmental precautions
|
Keep the product away from drains, the ground and watercourses. Contact the appropriate authority immediately if the product enters drains, lakes or watercourses.
|
Methods for cleaning up
|
Soak up using non-flammable absorbent material such as sand, earth, kieselguhr or vermikulite. Place in suitable, open container. Keep contents moist. Dispose of as directed under heading 13.
|
Other information
|
Remove all sources of ignition - No smoking. Provide good ventilation. Keep unauthorized persons away from the spillage. Warning for slippery surface.
|
|
|
7.
|
HANDLING AND STORAGE
Special properties and risks
|
The vapours are heavier than air and collect at floor level and low-lying areas. Flammable vapours that can combine with air to form an explosive mixture are produce at room temperature.
|
Advice for safe handling
|
Avoid contact with eyes, skin and clothing. Do not breathe vapours. Use only in well ventilated areas. Mechanical ventilation and spot extraction may be necessary. Store away from direct sunlight, heat, fire and other sources of ignition. Take precautionary measures against static discharges. Use only electrical equipment with explosion protection. See the instructions on the label.
|
Storage instructions
|
Store in a dry, well-ventilated place away from heat, fire and direct sunlight. No smoking. Electrical installations and equipment must have explosion protection. Follow regulations for storage of flammable liquids. Keep cool and dry, away from food, drink and animal feeding stuffs. Unauthorised persons must not have access to the storage area. Keep in original packaging. Keep container tightly closed.
|
|
|
8.
|
EXPOSURE CONTROLS/PERSONAL PROTECTION
Chemical name
|
Limit
|
Carbon black
|
3 mg/m
3
|
Ethylacetate
|
500 mg/m
3
|
Toluene
|
200 mg/m
3
|
Methyl ethyl ketone
|
150 mg/m
3
|
Solvent naphtha (petroleum), light
|
120 mg/m
3
|
Control procedures
|
Use only in well-ventilated areas. Spot extraction equipment or mechanical ventilation may be necessary. Do not smoke, eat or drink while working with the product. Good personal hygiene is essential. Wash hands before taking a break and on completion of the work. Take off contaminated clothing immediately. The use of a barrier cream is recommended.
|
Respiratory equipment
|
A full-face or half-face mask with filter for organic vapours must be used in case of high vapour concentrations or if ventilation is inadequate.
|
Eye protection
|
Close-fitting protective glasses with side shields must be used if there is a risk of direct contact or splashing.
|
Protective gloves
|
Solvent-resistant gloves. Use a barrier cream on skin.
|
Skin and body protection
|
Solvent-resistant protective clothing.
|
|
|
9.
|
PHYSICAL AND CHEMICAL PROPERTIES
Form/state
|
Liquid
|
Odour
|
Characteristic
|
Colour
|
Black
|
Solubility in water
|
Reacts with water
|
Flash point
|
-9 °C
|
Boiling point
|
77 °C
|
Explosion range
|
approx. 8.8-11.5 vol%
|
Vapour pressure
|
approx. 200 mbar at 20°C
|
Density
|
0.99 g/cm
3
|
Viscosity
|
< 16s/23°C/4 mm
|
Autoignition point
|
approx. 410°C
|
Vapour density (air=1)
|
approx. 2.5
|
|
|
10.
|
STABILITY AND REACTIVITY
Stability
|
Can react with the moisture in the air. Keep away from moisture. Vapours can form explosive mixture with air.
|
Reacts with
|
Avoid contact with other chemical products. Avoid contact with strong acids, amines and oxidizing agents.
|
Hazardous decomposition products
|
In case or fire or intense heat, carbon dioxide, carbon monoxide, nitrous oxides and toxic fumes are produced. Risk of peroxide mixtures.
|
|
|
11.
|
TOXICOLOGICAL INFORMATION
Inhalation
|
Irritating to the respiratory system. Inhalation may cause headaches, dizziness, drowsiness, muscular weakness, narcotic effects and, in exceptional cases, unconsciousness. Inhalation of high concentrations may damage the lever and kidneys and affect the central nervous system.
|
Skin
|
Prolonged or repeated skin contact defats the skin and may cause irritation and dermatitis. Substances in the product can be absorbed through the skin. Repeated exposure can cause sensitization and allergic reactions (eczema).
|
Eyes
|
Irritating to the eyes and may cause temporary damage.
|
Ingestion
|
If swallowed, may cause stinging in mouth and throat, nausea and stomach pains.
|
Sensitization
|
Sensitizing effects possible after inhalation or skin contact.
|
|
|
12.
|
ECOLOGICAL INFORMATION
Mobility
|
Insoluble in water.
|
Ecotoxicity
|
Test data for primary component, methyl ethyl ketone:
Fish toxicity: Leuciscus idus LC50 4600 mg/l
Toxicity for daphnia: D.Magna EC50 7060 mg/l
Toxicity for bacteria: Pseudomonas putida EC0 1150 mg/l
|
Other information
|
Do not empty into water, drains or onto ground.
|
|
|
13.
|
DISPOSAL CONSIDERATIONS
Disposal considerations
|
Dispose of product waste as hazardous waste in accordance with regulations. Recommended method of destruction: incineration in facilities with flue-gas purification. EWC-code 07 02 04, other organic solvents, washing liquids and mother liquors.
|
|
|
14.
|
TRANSPORT INFORMATION
Road (ADR)
|
UN-no.:
1139
Hazardous goods
Marg no.
|
Class:
3, 5 (b)
|
Label
Hazard no.
|
Rail (RID)
|
UN-no.:
1139
|
Class:
3, 5 (b)
|
Label
Hazard no.
|
Sea (IMDG)
|
UN-no.:
1139
Hazardous goods
Class:
3.2
EmS:
3-05
|
Page
MFAG:
300
Label
Marine poll:
No
|
Packaging group:
II
Sub. Risk
|
IATA (air)
|
UN-no.:
1139
Hazardous goods
|
Class:
3
Sub. Risk
|
Label
Packaging group:
II
|
Proper shipping name
|
Coating solution
|
|
|
15.
|
REGULATORY INFORMATION
Labelling
|
Irritant, Highly flammable
|
Contains
|
Contains isocyanates. See information from manufacturer.
|
References
|
See provisions of the Swedish National Board of Occupational Safety and Health on thermosetting plastics.
|
R-phrases
|
R11
|
Highly flammable.
|
|
|
R36
|
Irritating to eyes.
|
|
|
R66
|
Repeated exposure may cause skin dryness or cracking.
|
|
|
R67
|
Vapours may cause drowsiness and dizziness.
|
S-phases
|
S2
|
Keep out of the reach of children.
|
|
|
S16
|
Keep away from sources of ignition - No smoking.
|
|
|
S23
|
Do not breathe vapour/spray.
|
|
|
S37
|
Wear suitable gloves.
|
|
|
S46
|
If swallowed, seek medical advice immediately and show this container or label.
|
|
|
S51
|
Use only in well-ventilated areas.
|
|
|
16.
|
OTHER INFORMATION
General information
|
This material safety data sheet is only intended to provide guidance as to safe handling with regard to health, safety and the environment. The information contained in this material safety data sheet is not a specification of the product and must not be considered as a guarantee of any specific properties.
|
Issued
|
2001-05-01
|
|
|
Material safety data sheet
|
|
1.
|
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product name
|
BETAWIPE 4000
|
Manufacturer - supplier
|
SAAB-ANA Konsult AB
Box 1030
611 29 NYKÖPING
Tel: +46 (0) 155-24 94 50
Tel (emergency): 112
|
|
|
2.
|
COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient
|
CAS-no.
|
Content (%)
|
FM
|
FB
|
FH
|
R-phrases
|
Tris (p-isocyanatophenyl) thiophosphonate
|
4151-51-3
|
1-60
|
|
|
Xn
|
R42
|
Ethylacetate
|
41-78-6
|
60-90
|
|
|
Xi
|
R11-36-66-67
|
Key
|
FB/FH/FM = Hazard code for fire/health/environment
T+ = Very toxic
T = Toxic
C = Corrosive
Xn = Harmful
Xi = Irritant
V = Moderately harmful
IK = Not subject to labelling
E = Explosive
O = Oxidizing
F+ = Extremely flammable
F = Highly flammable
N = Dangerous for the environment
|
|
|
3.
|
HAZARDS IDENTIFICATION
Fire hazards
|
Highly flammable.
|
Health hazards
|
Irritating to eyes, skin and respiratory system. May cause sensitisation and allergic reaction by inhalation. Breathing high concentrations may cause dizziness, headaches and nausea. Defats the skin and after prolonged or repeated contact cause the skin to dry and crack.
|
|
|
4.
|
FIRST AID MEASURES
Other information
|
Take off contaminated clothing immediately.
|
Inhalation
|
Move the casualty into fresh air. Seek medical advice immediately. Effects may be delayed. Keep the casualty warm and allow to rest. Perform artificial respiration if the casualty stops breathing or breathes irregularly.
|
Skin
|
Wash skin immediately with soap and water. Seek medical advice if irritation persists.
|
Eyes
|
Flush eyes immediately with plenty of water for several minutes. Hold eyes wide open. Seek medical advice immediately.
|
Ingestion
|
Do not induce vomiting. Seek medical advice immediately.
|
|
|
5.
|
FIRE-FIGHTING MEASURES
Suitable extinguishing media
|
Foam, carbon dioxide or powder.
|
Unsuitable extinguishing media
|
Water is not suitable as an extinguishing media but may be used to cool containers in the vicinity of a fire, or to disperse vapours to protect firefighters or staff sealing leaks.
|
Fire/explosions risks
|
Vapours can form explosive mixture with air. In case of fire, flammable and irritating fumes can form (e.g. carbon oxides and ethanol).
|
Special protective equipment for firefighters
|
Complete protective equipment including respiratory equipment.
|
Other information
|
Do not breathe fumes from the fire. Move containers in the vicinity of the fire immediately or cool with water.
|
|
|
6.
|
SPILLAGE/ACCIDENTAL RELEASE MEASURES
Personal precautions
|
Avoid contact with skin, eyes and clothes. Do not breathe vapours. Wear the prescribed protective equipment (see heading 8).
|
Environmental precautions
|
Keep the product away from drains, the ground and watercourses. Contact the appropriate authority immediately if the product enters drains, lakes or watercourses.
|
Methods for cleaning up
|
Soak up using non-flammable absorbent material such as sand, earth, kieselguhr or vermikulite. Place in suitable container. Dispose of as directed under heading 13.
|
Other information
|
Remove all sources of ignition - No smoking. Provide good ventilation. Keep unauthorized persons away from the spillage. Warning for slippery surface.
|
|
|
7.
|
HANDLING AND STORAGE
Special properties and risks
|
The vapours are heavier than air and collect at floor level and low-lying areas. Flammable vapours that can combine with air to form an explosive mixture are produce at room temperature.
|
Advice for safe handling
|
Avoid contact with eyes, skin and clothing. Do not breathe vapours. Use only in well ventilated areas. Mechanical ventilation and spot extraction may be necessary. Store away from direct sunlight, heat, fire and other sources of ignition. Take precautionary measures against static discharges. Use only electrical equipment with explosion protection. See the instructions on the label.
|
Storage
|
Store in a dry, well-ventilated place away from heat, fire and direct sunlight. No smoking. Electrical installations and equipment must have explosion protection. Follow regulations for storage of flammable liquids. Keep cool and dry, away from food, drink and animal feeding stuffs. Unauthorised persons must not have access to the storage area. Keep in original packaging. Keep container tightly closed.
|
|
|
8.
|
EXPOSURE CONTROLS/PERSONAL PROTECTION
Chemical substance
|
Limit
|
Tris (p-isocyanatophenyl) thiophosphonate
|
0.05 mg/m
3
|
Ethylacetate
|
500 mg/m
3
|
Control procedures
|
Use only in well-ventilated areas. Spot extraction equipment or mechanical ventilation may be necessary. Do not smoke, eat or drink while working with the product. Good personal hygiene is essential. Wash hands before taking a break and on completion of the work. Take off contaminated clothing immediately. A barrier cream can be used.
|
Respiratory equipment
|
A full-face or half-face mask with filter for organic vapours must be used in case of high vapour concentrations or if ventilation is inadequate.
|
Eye protection
|
Close-fitting protective glasses with side shields must be used if there is a risk of direct contact or splashing.
|
Protective gloves
|
Solvent-resistant gloves. Use a barrier cream on skin.
|
Skin and body protection
|
Solvent-resistant protective clothing.
|
|
|
9.
|
PHYSICAL AND CHEMICAL PROPERTIES
Form/state
|
Liquid
|
Odour
|
Characteristic
|
Colour
|
Transparent
|
Solubility in water
|
approx 10% (reacts with water)
|
Density
|
0.93 g/cm
3
|
Flash point
|
-8 °C
|
Viscosity
|
50 s/23°C/4 mm
|
Explosion limits
|
approx. 2.1 - 11.5 vol%
|
Vapour pressure (at 20°C)
|
approx. 100 mbar
|
Boiling point
|
77 °C
|
Autoignition point
|
approx. 460°C
|
Vapour density (air=1)
|
3
|
|
|
10.
|
STABILITY AND REACTIVITY
Stability
|
Can react with the moisture in the air. Keep away from moisture. Vapours can form explosive mixture with air.
|
Reacts with
|
Keep away from other chemical products. Keep away from strong acids, amines, alcohols and oxidizing agents. Keep away from water.
|
Hazardous decomposition products
|
In case or fire or intense heat, carbon dioxide, carbon monoxide, nitrous oxides and toxic fumes are produced.
|
|
|
11.
|
TOXICOLOGICAL INFORMATION
Inhalation
|
Irritating to respiratory system. Inhalation may cause headaches, dizziness, drowsiness, muscular weakness, narcotic effects and, in exceptional cases, unconsciousness. Inhalation of high concentrations may damage the lever and kidneys and affect the central nervous system. May cause sensitization by inhalation of vapours/mist.
|
Skin
|
Prolonged or repeated skin contact defats the skin and may cause irritation and dermatitis. Substances in the product can be absorbed through the skin. Repeated exposure can cause sensitization and allergic reactions (eczema).
|
Eyes
|
Irritating to the eyes and may cause temporary damage.
|
Ingestion
|
If swallowed, may cause stinging in mouth and throat, nausea and stomach pains.
|
Sensitization
|
May cause sensitisation after inhalation or skin contact with the product.
|
|
|
12.
|
ECOLOGICAL INFORMATION
Degradability
|
The solvent, ethylacetate, decomposes readily.
|
Bioaccumulation
|
The solvent, ethylacetate, does not bioaccumulate. (Log Pow = 0.66)
|
Ecotoxicity
|
Fish toxicity: LC50 > 100 mg/l (regarding ethylacetate)
|
Other information
|
Do not empty into water, drains or onto ground.
|
|
|
13.
|
DISPOSAL CONSIDERATIONS
Disposal considerations
|
Dispose of product waste as hazardous waste in accordance with regulations. Recommended method of destruction: incineration in facilities with flue-gas purification.
|
EWC codes
|
07 02 04
other organic solvents, washing liquids and mother liquors.
|
Other information
|
Other codes may be relevant under certain circumstances.
|
|
|
14.
|
TRANSPORT INFORMATION
Road (ADR)
|
UN-no.:
1173
Hazardous goods
Marg no.
|
Class:
3, 53 (b)
|
Label
Hazard no.
|
Rail (RID)
|
UN-no.:
1173
|
Class:
3, 3 (b)
|
Label
Hazard no.
|
Sea (IMDG)
|
UN-no.:
1173
Hazardous goods
Class:
3.2
EmS:
3-07
|
Page
MFAG:
330
Label
Marine poll:
No
|
Packaging group:
II
Sub. Risk
|
IATA (air)
|
UN-no.:
1139
Hazardous goods
|
Class:
3
Sub. Risk
|
Label
Packaging group:
II
|
Proper shipping name
|
Ethylacetate mixture
|
|
|
15.
|
REGULATORY INFORMATION
Labelling
|
Harmful, Highly flammable
|
Content
|
Contains isocyanates. See information from manufacturer.
|
References
|
See provisions of the Swedish National Board of Occupational Safety and Health on thermosetting plastics.
|
R-phrases
|
R11
|
Highly flammable.
|
|
|
R36
|
Irritating to eyes.
|
|
|
R42
|
May cause sensitisation by inhalation.
|
|
|
R66
|
Repeated exposure may cause skin dryness or cracking.
|
|
|
R67
|
Vapours may cause drowsiness and dizziness.
|
S-phases
|
S2
|
Keep out of the reach of children.
|
|
|
S16
|
Keep away from sources of ignition - No smoking.
|
|
|
S23
|
Do not breathe vapour/spray.
|
|
|
S29
|
Do not empty into drains.
|
|
|
S37
|
Wear suitable gloves.
|
|
|
S45
|
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
|
|
|
S51
|
Use only in well-ventilated areas.
|
|
|
16.
|
OTHER INFORMATION
General information
|
This material safety data sheet is only intended to provide guidance as to safe handling with regard to health, safety and the environment. The information contained in this material safety data sheet is not a specification of the product and must not be considered as a guarantee of any specific properties.
|
Issued
|
2001-05-03
|
|
