PRE-RELEASE

30 08 075 Rubber moulding adhesive

/ 9-3 (9400) / 1999 / 0. General / Chemicals / Technical data / 30 08 075 Rubber moulding adhesive

Specifications

3M 8008. Black. 150 ml tube.

Saab application

Special adhesive for gluing rubber to metal and paint as well as repairing rubber mouldings.

Packaging

Transport

The product is classified as dangerous goods when transporting. Special regulations apply to packaging, marking and transport, therefore existing lead times cannot be guaranteed.

Directives

The product is highly flammable. Hazardous to personal health. Dangerous if inhaled. Irritates eyes. May cause skin irritation after frequently repeated exposure. The package should be firmly closed and stored in a cool and adequately ventilated area. The product must not be exposed to heat. Must be stored separately from materials which may ignite the product - Smoking is prohibited. Avoid inhaling vapours. Make sure that ventilation is adequate. Avoid skin and eye contact.

Material safety data sheet

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Trade name	08008 Super weatherstrip adhesive Black
Manufacturer - supplier	3M Svenska AB 191 89 Sollentuna Tel: +46 (0)8 92 21 00 Fax: +46 (0) 8 92 22 36

COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient	CAS-no.	Content (%)	Hazard symbol/R-phrases	Remarks
Methyl ethyl ketone (MEK)	78-93-3	20.0-30.0	F,Xi; R11-36-66-67	Exposure limit (AFS) set.
Naphtha (petroleum), solvent-refined light	64741-84-0	15.0-25.0	T; R45-65
Phenolic polymer	Trade Secret	10.0-25.0
Polychloroprene	9010-98-4	10.0-20.0
n-hexane	110-54-3	7.0-13.0	F,Xn,N;R11-38-48/20-51/53-62-65-67	Exposure limit (AFS) set.
Toluene	108-88-3	5.0-10.0	F,Xn; R11-20	Exposure limit (AFS) set (H).
Magnesium oxide	1309-48-4	1.0-10.0
2-chloro-1,3-butadiene polymers	Mixture	1.0-10.0
Xylene	1330-20-7	1.0-5.0	Xn; R10-20/21-38	Exposure limit (AFS) set (H).
Cyclohexane	110-82-7	<1.0	F,Xn,N R11-38-50/53-65-67	Exposure limit (AFS) set.
Carbon black	1333-86-4	0.1-0.5		Exposure limit (AFS) set.
Ethylbenzene	100-41-4	<0.2	F,Xn; R11-20	Exposure limit (AFS) set.

Key

FB/FH/FM = Hazard code for fire/health/environment

T+ = Very toxic

T = Toxic

C = Corrosive

Xn = Harmful

Xi = Irritant

V = Moderately harmful

IK = Not subject to labelling

E = Explosive

O = Oxidizing

F+ = Extremely flammable

F = Highly flammable

N = Dangerous for the environment

HAZARDS IDENTIFICATION

General information	The product is highly flammable. See section 15.
Adverse health effects	Irritating to eyes. Repeated exposure may cause skin dryness or cracking. Vapours can cause drowsiness and dizziness.
Adverse environmental effects	Toxic to aquatic organisms.

FIRST AID MEASURES

Inhalation	Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate medical attention.
Skin	Flush skin with large amounts of water. If irritation persists, get medical attention.
Eyes	Flush eyes immediately with plenty of water. Seek medical advice immediately.
Ingestion	Do not induce vomiting. Drink two glasses of water. Call a physician.

FIRE-FIGHTING MEASURES

Suitable extinguishing media	Carbon dioxide, powder, foam
Exposure hazards	Closed containers exposed to heat from fire may build pressure and explode. Vapours may travel long distances along the ground or floor to an ignition source and flash back.
Special firefighting procedures	Wear full protective equipment, including helmet and self-contained breathing apparatus.

SPILLAGE/ACCIDENTAL RELEASE MEASURES

Personal precautions	See other sections of this safety data sheet for information about health hazards, ventilation and personal protective equipment.
Measures	Extinguish all ignition sources. Cover with absorbent material. Collect using non-sparking tools. Ventilate area. Contain spill. Evacuate unprotected personnel from hazard area. Cover spill area with Light Water (3M brand) or other AFFF foam. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Place in an approved metal container. Seal the container.
Disposal	See under heading 13.

HANDLING AND STORAGE

Storage	Keep the container well sealed when not in use.
Materials/substances to avoid	Keep away from intense heat.
Fire prevention measures	Extremely flammable liquid and vapours.
Exposure control procedures	Keep away from heat, sparks, flames and other sources of ignition.
Precautionary measures against static discharges	Take precautionary measures against static discharges.
Handling instructions	Keep container tightly closed.

EXPOSURE CONTROLS/PERSONAL PROTECTION

Recommended ventilation	Do not use in a confined area or areas with little or no air movement. Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate, use appropriate respiratory protection.
Hand protection	Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: polyvinyl alcohol, fluoroelastomer (Viton).
Eye protection	Avoid eye contact. Wear vented goggles. Wear safety glasses with side shields.
Skin protection	Avoid skin contact.
Respiratory equipment	Avoid prolonged breathing of vapours. Select an approved respirator: half-mask organic vapour respirator, full-face organic vapour respirator.
Ingestion	Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest. Keep out of the reach of children.

PHYSICAL AND CHEMICAL PROPERTIES

Form/state	Viscous fluid	Odour	Solvent
Colour	Black	Boiling point/boiling point range	64.4-87.2°C
Flash point	-21.1°C	Explosion limit (low)	1.00 vol. %
Explosion limit (high)	11.50 vol. %	Vapour pressure	120.0000 mm Hg at 20°C
Solubility in water	Marginal	Density	0.90 (water=1)
Vapour density	3.00 (air=1)	Volatile organic compounds (VOC)	60.7 weight %
Evaporation rate	> 3.60 (ether=1)	Viscosity	7500.0 - 9500.0 centipoise

10.

STABILITY AND REACTIVITY

Stability and reactivity	Stable. No hazardous polymerisation.
Hazardous decomposition products	Carbon monoxide, carbon dioxide, toxic vapours, gases and particles.

11.

TOXICOLOGICAL INFORMATION

Inhalation	May be harmful if inhaled. Central nervous system depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended guidelines, may cause: Peripheral Neuropathy: signs/symptoms can include tingling of extremities, incoordination, numbness, weakness and tremors.
Skin	Moderate skin irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, itching, and dryness. May be absorbed through the skin and produce effects similar to those caused by inhalation and/or ingestion.
Eyes	Moderate eye irritation: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision.
Ingestion	Ingestion may cause: Irritation of gastrointestinal tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in faeces. Central nervous system depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions.
Cancer	The product contains a small quantity of carbon black. This substance may cause cancer. (IARC 2B)

12.

ECOLOGICAL INFORMATION

Environmental information

See under headings 2 and 15.

13.

DISPOSAL CONSIDERATIONS

Disposal	Treat as hazardous waste. Products of combustion contain hydrochloric acid. The facilities must be able to handle halogenated materials. Handle fully absorbed spillage as hazardous waste.
Packaging	3M Svenska AB is affiliated to all material companies that administer the collection of packaging. Contact Förpackningsinsamlingen tel. 0200-88 03 11 (Sweden only) for more information. Packaging labelled with a skull and crossbones, T+, T or risk phrase 50/53 must always be submitted for special treatment.

14.

TRANSPORT INFORMATION

If the product is classed as a dangerous good, the last page of the safety data sheet contains the heading "Transport information". 3M provides no transport information for goods that are shipped in unrestricted quantities. Contact the environmental department if required.

15.

REGULATORY INFORMATION

Hazard symbols

F (highly flammable), Xi (irritant)

R-phrases	R11	Highly flammable.
	R36	Irritating to eyes.
	R52	Toxic to aquatic organisms.
	R66	Repeated exposure may cause skin dryness or cracking.
	R67	Vapours may cause drowsiness and dizziness.
S-phases	S7/9	Keep container tightly closed in a cool, well-ventilated place.
	S16	Keep away from sources of ignition - No smoking.
	S23A	Do not breathe vapours.
	S24/25	Avoid contact with skin and eyes.
	S26	In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
	S28A	After contact with skin, wash immediately with plenty of soap and water.
	S33	Take precautionary measures against static discharges.
	S39A	Wear protective glasses.
	S51	Use only in well-ventilated areas.
	S53	NOTE: Avoid exposure - obtain special instructions before use.
	S61	Avoid release to the environment. Refer to special instructions/safety data sheets.
	S62	This material and its container must be disposed of as hazardous waste.
Content	Hexane isomers; methyl ethyl ketone, toluene
Comments	The product is not classed with R65 due to its viscosity. The constituent petroleum distillate does not require marking with R45 according to confirmation from the raw material supplier.
Internal reference number	E-1439

16.

OTHER INFORMATION

The information contained in this data sheet is based on the best information available and applies to the use and handling of the product. The user is responsible for all unspecified methods of handling and all use in combination with other products/processes.

Replaces	2000-06-30
Issued	2002-03-21

PRE-RELEASE

30 08 075 Rubber moulding adhesive

PRE-RELEASE

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