30 04 769 Bodywork adhesive
|
|
30 04 769 Bodywork adhesive
|
Teroson Teromix 6700 (T305). Dual-component polyurethane adhesive for gluing of body details.
Shaping of door panel.
1
No restrictions apply when transporting this product.
The product is hazardous to personal health. Contains isocyanates. Dangerous if inhaled. Irritates eyes, respiratory organs and skin. May cause allergic reaction if inhaled. Avoid inhaling vapours/mist. In case of eye contact, flush immediately with plenty of water and call a physician. In case of skin contact, wash immediately with soap and water. Make sure that ventilation is adequate.
|
Material safety data sheet
|
|
1.
|
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product name
|
Teromix 6700 (T305)
|
Application
|
Two-component adhesive in convenient twin cartridge.
|
Manufacturer - supplier
|
Loctite Sweden AB
Automotive Aftermarket
P.O. Box 8823
SE-402 71 GÖTEBORG
Tel: +46 31 750 54 00
|
|
|
2.
|
COMPOSITION/INFORMATION ON INGREDIENTS
This product contains:
Component A
|
polyhydric alcohols and filler.
|
Component B
|
filler, plasticiser, non-volatile isocyanate and non-volatile prepolymer isocyanate.
|
Component A
|
Ingredient
|
CAS-no.
|
Content (%)
|
Hazard symbol/R-phrases
|
Remarks
|
-
|
-
|
-
|
-
|
-
|
Component B
|
Ingredient
|
CAS-no.
|
Content (%)
|
Hazard symbol/R-phrases
|
Remarks
|
Diphenylmethane-4,4'-diisocyanate
|
101-68-8
|
< 25
|
Xn;R20 Xi;R36/37/38 R42/43
|
|
Butylbenzylphthalate
|
85-68-7
|
5-10
|
N;R50/53
|
|
Key
|
FB/FH/FM = Hazard code for fire/health/environment
T+ = Very toxic
T = Toxic
C = Corrosive
Xn = Harmful
Xi = Irritant
V = Moderately harmful
IK = Not subject to labelling
E = Explosive
O = Oxidizing
F+ = Extremely flammable
F = Highly flammable
N = Dangerous for the environment
|
|
|
3.
|
HAZARDS IDENTIFICATION
Adverse health effects
|
Component A
: May cause mild eye irritation. Prolonged contact with skin may cause temporary irritation.
|
Component B
: Contains non-volatile isocyanate. Heating produces vapours which may irritate the respiratory system and cause coughing, asthmatic breathing and shortness of breath. Respiratory allergy may develop from often repeated inhalation of vapours. May produce allergic reaction in contact with skin.
|
Adverse environmental effects
|
The product contains a substance that is very toxic to aquatic organisms and may cause long-term adverse effects to the aquatic environment.
|
|
|
4.
|
FIRST AID MEASURES
Inhalation
|
The person should rest in fresh air under supervision. In the event of discomfort, seek medical advice and take along this material safety data sheet. In case of persistent throat irritation or coughing, seek medical advice and take along this material safety data sheet.
|
Skin
|
Wash skin immediately. Rub thoroughly with liquid soap then rinse with plenty or lukewarm water.
|
Eyes
|
Rinse immediately with plenty of water for at least 15 minutes. Remove any contact lenses and keep the eyes wide open. If the irritation persists continue rinsing while on the way to hospital. Take along this material safety data sheet.
|
Ingestion
|
Rinse the mouth immediately and drink plenty of water, milk or cream. Keep the person under supervision. In case of discomfort, visit a hospital immediately and take along this material safety data sheet.
|
|
|
5.
|
FIRE-FIGHTING MEASURES
Suitable extinguishing media
|
Bear in mind the presence of other chemicals when selecting extinguishing media. If possible, remove the product from the vicinity of the fire and cool with water.
|
Specific hazards
|
Burning produces toxic vapours and corrosive gasses.
|
Special protective equipment for firefighters
|
In the event of firefighting, use respiratory equipment with an air supply.
|
|
|
6.
|
SPILLAGE/ACCIDENTAL RELEASE MEASURES
Personal precautions
|
A written plan shall exist for sanitation after accidents and leakages. The plan shall be made knows to the employees. Avoid contact with skin and eyes. See section 8 regarding personal protective equipment.
|
Environmental precautions
|
Do not empty into drains, onto land or in watercourses.
|
Methods for cleaning up
|
Scrape up spillages or remove with absorbent material. Neutralise spillages of the isocyanate component using a decontaminating agent such as a mixture of 50% ethanol, 5% concentrated ammoniac and 45% water. Waste or spillage containing the thermosetting plastic component or partially cured plastic must be dealt with immediately and placed in a special waste container. The container must have a lid and be clearly marked with the text "Harmful waste" and a text briefly describing the contents and precautionary measures. Refer to section 13 for disposal considerations.
|
|
|
7.
|
HANDLING AND STORAGE
Advice for safe handling
|
The handling of the thermosetting plastic component must be planned and carried out so that adequate safety precautions are taken preventing heath risks and accidents. Scrupulous personal hygiene is essential. Wash hands and contaminated areas with soap and water before leaving the workplace. Avoid contact with skin and eyes.
|
Technical measures
|
Use working methods that minimize contact. Technical aids: Use disposable equipment as far as possible (rags, brushes, pallet knives, etc.).
|
Technical information
|
Observe scrupulous personal hygiene. Shower facilities must be provided in the changing area. A wash basin must be provided close to the area of work and by the coffee room/rest area. Respiratory equipment must be tested by the individual and be provided by the workplace. Signs indicating that open handling is in progress must be put up. The thermosetting plastic component must be mixed in a sealed system or in a purpose-built, well-ventilated mixing area.
|
Storage instructions
|
No special measures required.
|
Storage conditions
|
Should be stored in sealed original packaging in a dry place.
|
|
|
8.
|
EXPOSURE CONTROLS/PERSONAL PROTECTION
Technical measures
|
Mixing and preparation must be carried out in a place with adequate extraction.
|
Component A
|
Chemical identity
|
Limit
|
Type
|
Comments
|
Ref.
|
-
|
-
|
-
|
-
|
-
|
Component B
|
Chemical identity
|
Limit
|
Type
|
Comments
|
Ref.
|
Isocyanates
|
0.005 ppm
|
NGV
|
S
|
AFS 2000:3
|
Respiratory equipment
|
In case of insufficient ventilation: Use respiratory equipment.
|
Hand protection
|
Wear disposable gloves with cotton gloves underneath to protect against isocyanates. Consult your glove supplier for suitable glove types.
|
Eye protection
|
If there is a risk of contact with eyes: Wear eye/face protection.
|
Skin protection
|
If there is a risk of contact: Wear a protective overall.
|
Hygiene measures:
|
Take off contaminated clothing and wash the skin thoroughly with soap and water after the completion of work.
|
|
|
9.
|
PHYSICAL AND CHEMICAL PROPERTIES
|
|
Component A
|
Component B
|
Form/state
|
Paste
|
Liquid
|
Colour
|
Beige
|
Black
|
Odour
|
Odourless
|
Characteristic
|
Relative density
|
1.43 g/cm
3
|
1.7 g/cm
3
|
Solubility in water
|
Insoluble
|
Insoluble
|
|
|
10.
|
STABILITY AND REACTIVITY
Stability
|
Stable at normal temperatures. Curing: 1-2 hours.
|
Conditions and material to avoid:
|
Heating.
|
Hazardous decomposition products
|
None at normal temperatures. Heating produces isocyanates and other toxic or harmful substances.
|
|
|
11.
|
TOXICOLOGICAL INFORMATION
Inhalation
|
Component A
: Not applicable.
|
Component B
: Contains non-volatile isocyanate. Heating produces vapours which may irritate the respiratory system and cause coughing, asthmatic breathing and shortness of breath. Respiratory allergy may develop from often repeated inhalation of vapours.
|
Skin contact
|
Component A
: Prolonged contact may cause redness and irritation.
|
Component B
: Irritating. Risk of developing hypersensitivity or triggering existing hypersensitivity.
|
Eye contact
|
Component A
: May cause temporary eye irritation.
|
Component B
: Irritating and may cause redness and stinging.
|
Ingestion
|
May cause irritation and nausea.
|
Prolonged exposure
|
Risk of developing hypersensitivity.
|
|
|
12.
|
ECOLOGICAL INFORMATION
Mobility
|
The product is insoluble in water and produces a sediment in aquatic environments.
|
Degradability
|
The product reacts with water to form a solid, insoluble product, which based on existing information is not degradable.
|
Ecotoxicity
|
The product contains butylbenzylphthalate which is very toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.
|
|
|
13.
|
DISPOSAL CONSIDERATIONS
Disposal considerations
|
Component B:
Dispose of waste as hazardous waste.
|
Surplus
|
Leave for controlled disposal, quoting EWC code 20 01 12.
|
Contaminated packaging
|
Treat contaminated packaging in the same way as surplus.
|
|
|
14.
|
TRANSPORT INFORMATION
Component A
The product is not included in international regulations for the transport of hazardous goods (IMDG, ICAO/IATA, ADR/RID).
Component B
UN-no.:
3077
|
Transport name:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S (Butylbenzylphthalate)
|
UN-no.:
3077
|
Transport name:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S (Butylbenzylphthalate)
|
Sea (IMDG)
|
Class:
9
EmS:
-
|
PG:
III
MFAG:
-
|
MP:
Yes
|
Inland waterways
|
To be handled locally.
|
Land (RID/ADR)
|
Class:
9
|
Substance number:
11
|
Letter:
c
|
Air (ICAO/IATA):
|
Class:
9
|
PG:
III
|
|
|
|
15.
|
REGULATORY INFORMATION
Component A
Labelling
|
Based on the information provided by the manufacturer regarding the chemical composition of the product, the Danish Toxicology Centre has judged that the product is not incorporated by the regulations of the Swedish National Chemicals Inspectorate on labelling, etc.
|
Component B
Labelling
|
Harmful
|
Contains
|
Diphenylmethane-4,4'-diisocyanate
|
R-phrases
|
R36/37/38
|
Irritating to eyes, respiratory system and skin.
|
|
|
R42/43
|
May cause sensitisation by inhalation and skin contact.
|
S-phases
|
S2
|
Keep out of the reach of children.
|
|
|
S23
|
Do not breathe vapours.
|
|
|
S36/37
|
Wear suitable protective clothing and gloves.
|
|
|
S45
|
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Contains isocyanates. See manufacturer's information.
|
Specific Swedish regulations:
|
Component B contains 60-100% non-volatile prepolymer isocyanate < 0.5% Diphenylmethanediisocyanate, isomers and homologues.
|
National regulations:
|
The Swedish National Chemicals Inspectorate's regulations accompanying the regulations (KIFS 1994:12) on the classification and labelling of chemical products, KIFS 1997:5 and KIFS 1999:3 with amendments. European Directives 67/548/EEC relating to dangerous substances and 88/379/EC relating to dangerous preparations (up to and including the 26th adaptation). The Swedish National Chemicals Inspectorate's Chemical Products and Biotechnical Organisms Regulations KIFS 1998:8, with amendments. Provisions of the Swedish National Board of Occupational Safety and Health on occupational exposure limits, AFS 2000:3. Provisions of the Swedish National Board of Occupational Safety and Health on thermosetting plastics, AFS 1996:4. Provisions of the Swedish National Board of Occupational Safety and Health on minors, together with general recommendations on the implementation of the provisions AFS 1996:1. Ordinance on dangerous waste (1996:971 with amendments).
|
|
|
16.
|
OTHER INFORMATION
General information
|
If nothing else is stated, the information in this material safety data sheet refers to the mixture for use. Work regulated by provisions on thermosetting plastics may only be lead and carried out by persons who have completed a special theoretical and practical course on the risks and safety provisions for such work. The user must be provided with guidance on performing the work and be acquainted with the contents of this material safety data sheet. The employer must, before the start of handing thermosetting plastics, arrange a medical examination for the employee, if the employee has not previously had such an examination. Minors under the age of 18 must not work with this product. The user must be provided with guidance on performing the work, the dangerous characteristics of the product and necessary safety precautions. The information contained in this safety data sheet is based on the information that was available at the time of preparation of this safety data sheet and is provided under the assumption that the product is used under the specified conditions and in accordance with the working methods specified on the packaging or in the relevant technical literature. All other use of this product, such as in conjunction with other products or in different processes, is undertaken at the risk of the user.
|
Issued
|
2000-12-13 by
DANISH TOXICOLOGY CENTRE
Kogle Allé 2
DK-2970 HØrsholm, Denmark.
Tel: +45 45 76 20 55
Fax: +45 45 76 24 55
|
|
