30 07 093 Body sealing compound
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30 07 093 Body sealing compound
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Teroson Terostat 1K-PUR. T226. White. Adhesive body sealant based on polyurethane. Used on visible joints. Does not shrink. Can be painted over also with 2K-paints. 310 ml cartridge.
For example, doors and wings.
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No restrictions apply when transporting this product.
Contains isocyanates. Repeated or prolonged contact with scratched or sensitive skin may cause allergic reactions. Avoid eye and skin contact.
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Material safety data sheet
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1.
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IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product name
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Terostat 1K-PUR (T226)
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Application
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Single-component sealant that cures through air humidity and remains elastic.
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Manufacturer - supplier
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Loctite Sweden AB
Automotive Aftermarket
P.O. Box 8823
SE-402 71 GÖTEBORG
Tel: +46 31 750 54 00
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2.
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COMPOSITION/INFORMATION ON INGREDIENTS
Product contains.: filler material, organic solvents, plasticizer, non-volatile isocyanate and non-volatile prepolymer isocyanate.
Ingredient
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CAS-no.
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Content (%)
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Hazard symbol/R-phrases
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Remarks
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Alphatic hydrocarbon (boiling point 173-193°C)
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90622-57-4
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10-30
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Xn; R65 R66
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Butylbenzylphthalate
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85-68-7
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5-10
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N;R50/53
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Xylene
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1330-20-7
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1-5
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R10 Xn;R20/21 Xi;R38
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Diphenylmethanediisocyanate, isomers and homologues.
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9016-87-9
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<0.5
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Xn;R20 Xi;R36/37/38 R42/43
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Key
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FB/FH/FM = Hazard code for fire/health/environment
T+ = Very toxic
T = Toxic
C = Corrosive
Xn = Harmful
Xi = Irritant
V = Moderately harmful
IK = Not subject to labelling
E = Explosive
O = Oxidizing
F+ = Extremely flammable
F = Highly flammable
N = Dangerous for the environment
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3.
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HAZARDS IDENTIFICATION
Adverse health effects
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Contains non-volatile isocyanates. Heating produces vapours which may irritated the respiratory system and produce coughing, asthmatic breathing and shortness of breath. Respiratory allergy may develop from often repeated inhalation of vapours. The product contains organic solvents. High concentrations of vapours may cause drowsiness and can give rise to headaches, tiredness, dizziness and nausea.
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Adverse environmental effects
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This product contains volatile organic compounds that can contribute to the photochemical formation of ozone. The product contains a substance that is very toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.
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4.
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FIRST AID MEASURES
Inhalation
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The person should rest in fresh air under supervision. In the event of discomfort, seek medical advice and take along this material safety data sheet. In case of persistent throat irritation or coughing, seek medical advice and take along this material safety data sheet.
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Skin
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Wash skin immediately: Rub thoroughly with liquid soap and rinse carefully with lukewarm water. In case of eczema or other skin condition: Seek medical advice (show this material safety data sheet where possible).
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Eyes
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Rinse immediately with plenty of water for at least 15 minutes. Remove any contact lenses and keep the eyes wide open. If the irritation persists: Visit a hospital and present this material safety data sheet.
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Ingestion
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Rinse the mouth immediately and drink plenty of water, milk or cream. Keep the person under supervision. In case of discomfort, visit a hospital immediately and take along this material safety data sheet.
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5.
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FIRE-FIGHTING MEASURES
Suitable extinguishing media
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Use a carbon dioxide or powder extinguisher. If exposed to heat, cool containers with water and remove from the area of fire, if this is possible without entailing risk.
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Specific hazards
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Burning produces toxic vapours and corrosive gasses.
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Special protective equipment for firefighters
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In the event of firefighting, use respiratory equipment with an air supply.
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6.
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SPILLAGE/ACCIDENTAL RELEASE MEASURES
Personal precautions
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A written plan shall exist for sanitation after accidents and leakages. The plan shall be made knows to the employees. Ventilation shall be adequate. See section 8 regarding personal protective equipment.
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Environmental precautions
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Do not empty into drains, onto land or in watercourses.
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Methods for cleaning up
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Scrape up spillages or remove with absorbent material. Neutralise spillages of the isocyanate component using a decontaminating agent such as a mixture of 50% ethanol, 5% concentrated ammoniac and 45% water. Waste or spillage containing the thermosetting plastic component or partially cured plastic must be dealt with immediately and placed in a special waste container. The container must have a lid and be clearly marked with the text "Harmful waste" and a text briefly describing the contents and precautionary measures. Refer to section 13 for disposal considerations.
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7.
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HANDLING AND STORAGE
Advice for safe handling
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The handling of the thermosetting plastic component must be planned and carried out so that adequate safety precautions are taken preventing heath risks and accidents. Avoid inhalation and contact with skin and eyes.
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Technical measures
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Use working methods that minimize contact. Technical aids: Use disposable equipment as far as possible (rags, brushes, pallet knives, etc.).
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Technical information
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Observe scrupulous personal hygiene. Shower facilities must be provided in the changing area. A wash basin must be provided close to the area of work and by the coffee room/rest area. Respiratory equipment must be tested by the individual and be provided by the workplace. Signs indicating that open handling is in progress must be put up.
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Storage instructions
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No special measures required.
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Storage conditions
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Must be stored in sealed original packaging at a temperature between 5°C and 25°C.
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8.
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EXPOSURE CONTROLS/PERSONAL PROTECTION
Technical measures
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Efficient ventilation must be provided. Limits must not be exceeded and the risk of breathing vapours must be minimized.
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Chemical identity
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Limit
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Type
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Comments
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Ref.
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Nonanes
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150ppm 800mg/m³
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NGV
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AFS 2000:3
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Xylene
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50ppm 200mg/m³
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NGV
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H
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AFS 2000:3
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Isocyanates
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0.005ppm
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NGV
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S
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AFS 2000:3
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Respiratory equipment
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In case of insufficient ventilation: Use respiratory equipment.
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Hand protection
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Wear disposable gloves with cotton gloves underneath to protect against isocyanates. Consult your glove supplier for suitable glove types.
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Eye protection
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If there is a risk of contact with eyes: Wear eye/face protection.
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Skin protection
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If there is a risk of contact: Wear a protective overall.
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Hygiene measures:
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Take off contaminated clothing and wash the skin thoroughly with soap and water after the completion of work.
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9.
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PHYSICAL AND CHEMICAL PROPERTIES
Form/state
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Paste
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Odour
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Aromatic hydrocarbon
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Colour
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White
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Solubility in water
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Insoluble
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Relative density
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1.16 g/cm
3
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Flash point
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44°C
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Solubility
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Soluble in aromatic solvent
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10.
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STABILITY AND REACTIVITY
Stability
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Stable at normal temperatures. Curing: 6 mm/24 hrs
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Conditions and material to avoid:
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Heating.
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Hazardous decomposition products
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None at normal temperatures. Heating produces isocyanates and other toxic or harmful substances.
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11.
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TOXICOLOGICAL INFORMATION
Inhalation
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Contains non-volatile isocyanates. Heating produces vapours which may irritated the respiratory system and produce coughing, asthmatic breathing and shortness of breath. Respiratory allergy may develop from often repeated inhalation of vapours. The product contains organic solvents. High concentrations of vapours may cause drowsiness and can give rise to headaches, tiredness, dizziness and nausea.
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Skin
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May irritate skin. The product contains a small quantity of allergenic substances that can cause allergic reactions in sensitive individuals.
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Eyes
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May irritate and produce redness and stinging.
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Ingestion
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May cause irritation and nausea.
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Prolonged exposure
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Frequent repeated inhalation of even low concentrations can produce irritation, tiredness and memory loss and with time permanent damage to the nervous system, including the brain. Risk of developing hypersensitivity.
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12.
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ECOLOGICAL INFORMATION
Mobility
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The product is insoluble in water and produces a sediment in aquatic environments. The product contains volatile organic compounds (VOC) that evaporate rapidly from all surfaces.
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Degradability
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Degradability of product unknown.
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Ecotoxicity
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This product contains volatile organic compounds that can contribute to the photochemical formation of ozone. The product contains a substance that is very toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.
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13.
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DISPOSAL CONSIDERATIONS
Dispose of waste as hazardous waste.
Surplus
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Leave for controlled disposal, quoting EWC code 20 01 12.
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Contaminated packaging
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Treat contaminated packaging in the same way as surplus.
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14.
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TRANSPORT INFORMATION
The product is not included in international regulations for the transport of hazardous goods (IMDG, ICAO/IATA, ADR/RID).
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15.
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REGULATORY INFORMATION
Contains
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Diphenylmethanediisocyanate, isomers and homologues. Contains isocyanates. See manufacturer's information.
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Labelling
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Harmful
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R-phrases
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R42
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May cause sensitisation by inhalation.
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R66
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Repeated exposure may cause skin dryness or cracking.
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S-phases
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S2
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Keep out of the reach of children.
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S23
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Do not breathe vapours.
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S45
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Contains isocyanates. See manufacturer's information. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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Specific Swedish regulations:
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Contents: 60-100 % non-volatile prepolymer isocyanate < 0.5 % Diphenylmethanediisocyanate, isomers and homologues.
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National regulations:
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European Directives 67/548/EEC relating to dangerous substances and 88/379/EC relating to dangerous preparations (up to and including the 26th adaptation). The Swedish National Chemicals Inspectorate's regulations accompanying the regulations (KIFS 1994:12) on the classification and labelling of chemical products, KIFS 1997:5 and KIFS 1999:3 with amendments. The Swedish National Chemicals Inspectorate's Chemical Products and Biotechnical Organisms Regulations KIFS 1998:8, with amendments. Provisions of the Swedish National Board of Occupational Safety and Health on occupational exposure limits, AFS 2000:3. Provisions of the Swedish National Board of Occupational Safety and Health on thermosetting plastics, AFS 1996:4. Provisions of the Swedish National Board of Occupational Safety and Health on minors, together with general recommendations on the implementation of the provisions AFS 1996:1. Ordinance on dangerous waste (1996:971 with amendments).
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16.
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OTHER INFORMATION
General information
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The employer must, before the start of handing thermosetting plastics, arrange a medical examination for the employee, if the employee has not previously had such an examination. Work regulated by provisions on thermosetting plastics may only be lead and carried out by persons who have completed a special theoretical and practical course on the risks and safety provisions for such work. Minors under the age of 18 must not work with this product. The user must be provided with guidance on performing the work, the dangerous characteristics of the product and necessary safety precautions. The information contained in this safety data sheet is based on the information that was available at the time of preparation of this safety data sheet and is provided under the assumption that the product is used under the specified conditions and in accordance with the working methods specified on the packaging or in the relevant technical literature. All other use of this product, such as in conjunction with other products or in different processes, is undertaken at the risk of the user.
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Issued
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2000-12-18 by
DANISH TOXICOLOGY CENTRE
Kogle Allé 2
DK-2970 HØrsholm, Denmark.
Tel: +45 45 76 20 55
Fax: +45 45 76 24 55
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